Polyether polymerization process

ABSTRACT

Embodiments relate to a method of producing a modified double metal cyanide complex, a method of producing a monol or polyol that includes providing the modified double metal cyanide complex, an alkylene oxide polymerization process that includes providing the modified double metal cyanide complex, a batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex, and a polyether polyol prepared using the batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex.

This invention relates to processes for polymerizing alkylene oxides to form polyethers.

Poly(alkylene oxides) are produced globally in large quantities by polymerizing one or more alkylene oxides in the presence of a polymerization catalyst. They are important raw materials for producing polyurethanes and are used as surfactants and industrial solvents, among other uses. The predominant polymerization catalysts are alkali metal hydroxides or alkoxides and certain metal complexes that are commonly referred to as double metal cyanide (DMC) catalysts.

Double metal cyanide catalysts have certain advantages. They do not strongly catalyze a rearrangement of propylene oxide to form propenyl alcohol. Polyether polyols made using DMC catalysts therefore tend to have lower quantities of unwanted monofunctional polymers. In addition, DMC catalyst residues usually do not need to be removed from the product. Doing so avoids neutralization and catalyst removal steps that are needed when alkali metal catalysts are used.

DMC catalysts have certain disadvantages, however. They exhibit a latency period after being exposed to an alkylene oxide under polymerization conditions before they become “activated” and rapid polymerization begins. Another significant problem is that DMC catalysts perform sluggishly in the presence of high concentrations of hydroxyl groups. For this reason, DMC catalysts are disfavored when making low molecular weight products and in semi-batch processes that begin with low equivalent weight starters.

U.S. Pat. No. 9,040,657 discloses a method of producing a polyether monol or polyol in the presence of the DMC catalyst and a magnesium, Group 3-Group 15 metal or lanthanide series compound in which a magnesium, Group 3-Group 15 metal or lanthanide series metal is bonded to at least one alkoxide, aryloxy, carboxylate, acyl, pyrophosphate, phosphate, thiophosphate, dithiophosphate, phosphate ester, thiophosphate ester, amide, siloxide, hydride, carbamate or hydrocarbon anion, and the magnesium, Group 3-Group 15 or lanthanide series metal compound being devoid of halide anions. This technology is very effective in reducing the activation time and in improving the catalyst performance when exposed to high concentrations of hydroxyl groups. However, adding the second component of the catalyst system into the polymerization reaction requires additional equipment for storing and metering. Because of the small amounts that are needed, precise control over the addition of the second component can be difficult.

Subhani et al., in Eur. J. Inorg. Chem., 2016, 1944-1949, describe hybrid TiO₂-DMC hybrid catalysts and their use in copolymerizing propylene oxide and carbon dioxide to form polycarbonates. A hybrid SiO₂-DMC catalyst, also for polycarbonate production, is described by Dienes et al. in Green Chem. 2012, 14, 1168.

U.S. Pat. No. 6,780,813 discloses a process of preparing a DMC catalyst that includes the steps of forming a DMC catalyst dispersion while using an additional piece of equipment not typically used, i.e., a jet disperser, to dispense liquid solutions of at least one water soluble salt of Zn(II), Fe(II), Ni(II), Mn(II), Co(II), Sn(II), Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(V), V(IV), Sr(II), W(IV), W(VI), Cu(II) or Cr(III); and at least one solution of at least one water-soluble metal cyanide salt or at least one alkali or alkaline-earth metal cyanide acid of Fe(II), Fe(III), Co(II), Co(III), Cr(II), Cr(III), Mn(II), Mn(III), Ir(III), Ni(II), Rh(III), Ru(II), V(IV) or V(V). Improvements are sought that enable the introduction of additives into a catalyst without the use of specialized equipment, such as jet dispersers.

This invention is a method for producing a polyether, the method forming a reaction mixture comprising a hydroxyl-containing starter, at least one alkylene oxide and a catalyst complex, and polymerizing the alkylene oxide onto the hydroxyl-containing starter to produce the polyether in the presence of no more than 0.01 moles of a carbonate precursor per mole of alkylene oxide, wherein the catalyst complex is selected from the group consisting of catalyst complexes I, II and III, wherein

catalyst complex I is a catalyst complex produced in a method comprising:

a) forming a starting solution comprising i) a solvent that includes at least one of water and a liquid aliphatic alcohol, the solvent having dissolved therein ii) a cyanometallate compound having an M² metal cyanometallate group and iii) a M¹ metal salt which reacts with the cyanometallate compound to form a water-insoluble M¹ metal cyanometallate, which starting solution further contains 0.01 to 10 moles, per mole of cyanometallate compound, of iii) at least one M³ metal or semi-metal compound different from the M¹ metal salt, the M³ metal or semi-metal compound being a compound of a M³ metal or semi metal, the M³ metal or semi-metal being selected from one or more of magnesium, a Group 3-Group 15 metal or semi-metal, or a lanthanide series metal which the M³ metal or semi-metal is bonded to at least one alkoxide, aryloxy, carboxylate, acyl, pyrophosphate, phosphate, thiophosphate, dithiophosphate, phosphate ester, thiophosphate ester, amide, oxide, siloxide, hydride, carbamate or hydrocarbon anion, and the M³ metal or semi-metal compound is devoid of halide anions; and

b) reacting the cyanometallate compound and M¹ metal salt to form a water-insoluble catalyst complex that includes a M¹ metal cyanometallate;

catalyst complex II corresponds to the formula: M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(c)[M⁵(X²)₆]_(d) ·nM⁴ _(x)A¹ _(y) ·pM³ _(w)A² _(z) wherein: M¹ and M⁴ each represent a metal ion independently selected from Zn²⁺, Fe²⁺, Co⁺²⁺, Ni²⁺, Mo⁴⁺, Mo⁶⁺, Al⁺³⁺, V⁴⁺, V⁵⁺, Sr²⁺, W⁴⁺, W⁶⁺, Mn²⁺, Sn²⁺, Sn⁴⁺, Pb²⁺, Cu²⁺, La³⁺, and Cr³⁺; M² and M⁵ each represent a metal ion independently selected from Fe³⁺, Fe²⁺, Co³⁺, Co²⁺, Cr²⁺, Cr³⁺, Mn²⁺, Mn³⁺, Ir³⁺, Ni²⁺, Rh³⁺, Ru²⁺, V⁴⁺, V⁵⁺, Ni²⁺, Pd²⁺, and Pt²⁺; M³ represents at least one magnesium, Group 3-Group 15 metal, or lanthanide series metal or semi-metal ion; X¹ represents a group other than cyanide that coordinates with the M² ion; X² represents a group other than cyanide that coordinates with the M⁵ ion; A¹ represents a halide, nitrate, sulfate, carbonate, cyanide, oxalate, thiocyanate, isocyanate, perchlorate, isothiocyanate, an alkanesulfonate, an arylenesulfonate, trifluoromethanesulfonate, or a C₁₋₄ carboxylate; A² represents least one alkoxide, aryloxy, carboxylate, acyl, pyrophosphate, phosphate, thiophosphate, amide, oxide, siloxide, hydride, carbamate, or hydrocarbon anion; b, c and d are each numbers that reflect an electrostatically neutral complex, provided that b and c each are greater than zero; x and y are integers that balance the charges in the metal salt M³ _(x)A¹ _(y); r is an integer from 4 to 6; t is an integer from 0 to 2; n is a number from 0 and 20; p is from 0.002 to 10; and w and z are integers that balance the charges in the metal salt M³ _(z)A² _(z), provided that w is from 1 to 4; and

catalyst complex III is a mixture of a zinc hexacyanocobaltate catalyst and a particulate M³ metal or semi-metal oxide wherein the M³ metal or semi-metal is at least one of magnesium, Group 3-Group 15 metal or semi-metal or lanthanide series metal ion and the M³ metal or semi-metal oxide is present in an amount sufficient to provide 0.002 to 10 moles of M³ metal or semi-metal per mole of cobalt provided by the zinc hexacyanocobaltate catalyst . . . .

Several important advantages are obtained with the invention. The time required to activate the catalyst is short. Once the catalyst is activated, the polymerization proceeds rapidly. These advantages are seen (and in fact are most prominent) under conditions in which conventional zinc hexacyanocobaltate catalysts perform sluggishly if at all. Those conditions include the presence of low equivalent weight starters and/or the presence of high concentrations of hydroxyl groups during at least a portion of the polymerization reaction. In many cases, the high activity of the catalyst allows it to be used in very small amounts, while still achieving fast polymerization kinetics. The excellent activity permits very small catalyst loadings to be used. The selection of the catalyst complex in accordance with the invention may also reduce the formation of a high molecular weight fraction, the formation of which plagues the use of conventional zinc hexacyanocobaltate catalysts.

FIG. 1 illustrates a graphical representation of reactor pressure and propylene oxide feed rate vs. time for a propylene oxide polymerization using a prior art catalyst (Comparative Sample C).

FIG. 2 illustrates a graphical representation of reactor pressure and propylene oxide feed rate vs. time for propylene oxide polymerization using a catalyst complex of the invention (Example 1).

FIG. 3 illustrates a graphical representation of reactor pressure and propylene oxide feed rate vs. time for propylene oxide polymerization using a catalyst complex of the invention (Example 14).

Polyethers are prepared according to the invention in a process that comprises: (1) combining the catalyst complex with an alcoholic starter compound and an alkylene oxide to form a polymerization mixture, and then subjecting the polymerization mixture to polymerization conditions.

The polymerization is performed in the presence of no more than 0.01 mole of a carbonate precursor per mole of alkylene oxide that is polymerized. Accordingly, the polyether formed in the process has few if any carbonate linkages. The polymerization in some embodiments is performed in the presence of no more than 0.001 moles of a carbonate precursor or no more than 0.0001 moles of a carbonate precursor, per mole of alkylene oxide that is polymerized. The carbonate precursor may be absent entirely.

A “carbonate” precursor is a compound that gives rise to carbonate (—O—C(O)—O—) linkages when polymerized with an alkylene oxide. Examples of carbonate precursors include carbon dioxide, linear carbonates, cyclic carbonates, phosgene and the like.

The polyether formed in the process may have up to 0.5 weight-% CO₂ in the form of carbonate linkages. It preferably contains no more than 0.1 weight-% of such CO₂ and may contain no more than 0.01 weight-% of such CO₂. It may contain no such CO₂.

The main functions of the starter compound are to provide molecular weight control and to establish the number of hydroxyl groups that the polyether product will have. A hydroxyl-containing starter compound may contain 1 or more (e.g., 2 or more) hydroxyl groups and as many as 12 or more hydroxyl groups. For example, starters for producing polyols for use in polyurethane applications usually have from 2 to 8 hydroxyl groups per molecule. In some embodiments, the starter compound will have from 2 to 4 or from 2 to 3 hydroxyl groups. In other embodiments, the starter compound will have from 4 to 8 or from 4 to 6 hydroxyl groups. The starter compound may have at least two hydroxyl groups that are in the 1,2- or 1,3-positions with respect to each other (taking the carbon atom to which one of the hydroxyl groups is bonded as the “1” position). Mixtures of starter compounds can be used.

The starter compound will have a hydroxyl equivalent weight less than that of the monol or polyol product. It may have a hydroxyl equivalent weight of from 30 to 500 or more. The equivalent weight may be up to 500, up to 250, up to 125, and/or up to 100.

Exemplary starters include, but are not limited to, glycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1,4-butane diol, 1,6-hexane diol, 1,8-octane diol, cyclohexane dimethanol, glycerin, trimethylolpropane, trimethylolethane, pentaerythritol, sorbitol, sucrose, phenol and polyphenolic starters such as bisphenol A or 1,1,1-tris(hydroxyphenyl)ethane, and alkoxylates (such as ethoxylates and/or propoxylates) of any of these that have a hydroxyl equivalent weight less than that of the product of the polymerization. The starter compound can also be water. The starter may be neutralized with or contain a small amount of an acid, particularly if the starter is prepared in the presence of a base (as is often the case with glycerin). If an acid is present, it may be present in an amount of from about 10 to 100 ppm, based on the weight of the starter, e.g., as described in U.S. Pat. No. 6,077,978. The acid may be used in somewhat larger amounts, such as from 100 to 1000 ppm, based on the weight of the starter, as described in U.S. Patent Publication Application No. 2005-0209438. The acid may be added to the starter before or after the starter is combined with the catalyst complex.

Certain starters may provide specific advantages. Triethylene glycol has been found to be an especially good starter for use in batch and semi-batch processes for producing polyether diols. Tripropylene glycol and dipropylene glycol also have been found to be especially good starters for use in conjunction with the catalyst complex of the invention.

The alkylene oxide may be, e.g., ethylene oxide, 1,2-propylene oxide, 2,3-propylene oxide, 1,2-butane oxide, 2-methyl-1,2-butaneoxide, 2,3-butane oxide, tetrahydrofuran, epichlorohydrin, hexane oxide, styrene oxide, divinylbenzene dioxide, a glycidyl ether such as Bisphenol A diglycidyl ether, allyl glycidyl ether, or other polymerizable oxirane. The preferred alkylene oxide is 1,2-propylene oxide, or a mixture of at least 40% (preferably at least 80%) by weight propylene oxide and up to 60% by weight (preferably up to 20%) ethylene oxide.

The polymerization typically is performed at an elevated temperature. The polymerization mixture temperature may be, for example, 80 to 220° C. (e.g., from 120 to 190° C.).

The polymerization reaction usually may be performed at superatmospheric pressures, but can be performed at atmospheric pressure or even sub-atmospheric pressures. A preferred pressure is 0 to 10 atmospheres, especially 0-6 atmospheres, gauge pressure.

The polymerization preferably is performed under vacuum or under an inert atmosphere such as a nitrogen, helium or argon atmosphere. Carbon dioxide is either absent or present in at most an amount as indicated above with regard to carbonate precursors.

Enough of the catalyst complex may be used to provide a reasonable polymerization rate, but it is generally desirable to use as little of the catalyst complex as possible consistent with reasonable polymerization rates, as this both reduces the cost for the catalyst and, if the catalyst levels are low enough, can eliminate the need to remove catalyst residues from the product. Using lower amounts of catalysts also reduces the residual metal content of the product. The amount of catalyst complex may be from 1 to 5000 ppm based on the weight of the product. The amount of catalyst complex may be at least 2 ppm, at least 5 ppm, at least 10 ppm, at least 25 ppm, or up to 500 ppm or up to 200 ppm or up to 100 ppm, based on the weight of the product. The amount of catalyst complex may be selected to provide 0.25 to 20, 0.5 to 10, 0.5 to 1 or 0.5 to 2.5 parts by weight cobalt per million parts by weight of the product.

The polymerization reaction may be performed in any type of vessel that is suitable for the pressures and temperatures encountered. In a continuous or semi-batch process, the vessel should have one or more inlets through which the alkylene oxide and additional starter compound and catalyst complex can be introduced during the reaction. In a continuous process, the reactor vessel should contain at least one outlet through which a portion of the partially polymerized reaction mixture can be withdrawn. In a semi-batch operation, alkylene oxide (and optionally additional starter and catalyst complex) is added during the reaction, but product usually is not removed until the polymerization is completed. A tubular reactor that has multiple points for injecting the starting materials, a loop reactor, and a continuous stirred tank reactor (CTSR) are all suitable types of vessels for continuous or semi-batch operations. The reactor should be equipped with a means of providing or removing heat, so the temperature of the reaction mixture can be maintained within the required range. Suitable means include various types of jacketing for thermal fluids, various types of internal or external heaters, and the like. A cook-down step performed on continuously withdrawn product is conveniently conducted in a reactor that prevents significant back-mixing from occurring. Plug flow operation in a pipe or tubular reactor is a preferred manner of performing such a cook-down step.

The product obtained in any of the foregoing processes may contain up to 0.5% by weight, based on the total weight, of unreacted alkylene oxide; small quantities of the starter compound and low molecular weight alkoxylates thereof; and small quantities of other organic impurities and water. Volatile impurities should be flashed or stripped from the resultant monol or polyol. The product typically contains catalyst residues. It is typical to leave these residues in the product, but these can be removed if desired. Moisture and volatiles can be removed by stripping the polyol.

The polymerization reaction can be characterized by the “build ratio”, which is defined as the ratio of the number average molecular weight of the product to that of the starter compound. This build ratio may be as high as 160, but is more commonly in the range of from 2.5 to about 65 and still more commonly in the range of from 2.5 to about 50, from 2.5 to 35, from 2.5 to 11 or from 7 to 11.

The invention is particularly useful in polymerization processes characterized by one or more of the following: i) the use of a starter having an equivalent weight of up to 125, especially up to 100 or up to 75; ii) a hydroxyl content of 4.25 to 20 wt. %, especially 4.25 to 15 wt. %, based on the total weight of the reaction mixture, during at least a portion of the polymerization process, and iii) a concentration of catalyst complex sufficient to provide at most 5 ppm of cobalt, especially 0.5 to 2 ppm, based on the weight of the product. Each of these represents a severe condition in which conventional zinc hexacyanometallate catalysts perform poorly.

The catalyst complex in some embodiments is one made in a precipitation process in which a solution containing the starting materials is prepared, certain of the starting materials react and the catalyst complex precipitates from the starting solution. In general, methods for producing DMC catalyst as described, e.g., in U.S. Pat. Nos. 3,278,457, 3,278,458, 3,278,459, 3,404,109, 3,427,256, 3,427,334, 3,427,335, and 5,470,813, can be adapted to make the catalyst complex of this invention by incorporating the M³ metal or semi-metal compound into the starting solutions used to prepare those catalysts.

The solvent includes at least one of water and a liquid aliphatic alcohol. The solvent is one in which the starting cyanometallate compound and M¹ metal compound are soluble. The solvent may or may not be a solvent for the M³ metal or semi-metal compound.

The solvent may be, for example, water, n-propanol, iso-propanol, n-butanol, sec-butanol, t-butanol, other alkylene monoalcohol having up to, for example, 12 carbon atoms, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, or other polyether having one or more hydroxyl groups and a molecular weight of up to, for example, 8000 g/mol. Aliphatic monoalcohols having 3 to 6 carbon atoms, especially t-butanol, are preferred among these. Especially preferred is a mixture of water and a liquid aliphatic alcohol that is soluble in water at the relative proportions present in the mixture (especially an aliphatic monoalcohol having 3 to 6 carbon atoms and most preferably t-butanol), in a volume ratio of 25:75 to 90:10.

The starting solution is conveniently formed by forming separate solutions of the starting cyanometallate compound and the M¹ metal compound and combining them. The M³ metal or semi-metal compound is conveniently added to one or the other of these separate solutions, preferably the M¹ metal or semi-metal compound solution. The combining of the starting solution should be accompanied by mixing. It is generally preferred to mix the cyanometallate compound solution into the solution of the M¹ metal compound, preferably by gradually adding the cyanometallate compound solution so the M¹ metal compound is always present in excess.

It is preferred to provide an excess of the M¹ metal compound over the cyanometallate compound. In some embodiments, the mole ratio of M¹ metal compound to cyanometallate compound is at least 2:1, preferably at least 3:1 or at least 5:1. This ratio may be, for example, up to 20:1 or up to 15:1.

The starting solution contains, prior to reaction, 0.01 to 10 moles of the M³ metal or semi-metal compound per mole of cyanometallate compound. Smaller amounts do not lead to any improvement in the performance of the catalyst complex. Larger amounts not only fail to improve the catalyst performance but actually tend to diminish it.

The cyanometallate compound and M¹ metal compound react to form a catalyst complex that includes a water-insoluble M¹ metal cyanometallate. This reaction proceeds spontaneously at temperatures around room temperature (23° C.) or slightly elevated temperatures. Therefore, no special reaction conditions are needed. The temperature may be, for example, from 0 to 60° C. A preferred temperature is 20 to 50° C. or 25 to 45° C. It is preferred to continue agitation until precipitation takes place, which is generally indicated by a change of appearance in the solution. The reaction pressure is not especially critical so long as the solvent does not boil off. A pressure of 10 to 10,000 kPa is suitable, with a pressure of 50 to 250 kPa being entirely suitable. The reaction time may be from 30 minutes to 24 hours or more.

In some cases, the M³ metal or semi-metal compound may react during the catalyst preparation step. For example, certain M³ metal or semi-metal compounds may react with water during the catalyst preparation to form the corresponding metal oxide. The M³ metal or semi-metal compound or reaction product thereof (especially an M³ metal or semi-metal oxide) in some embodiments forms, together with a reaction product of the M¹ metal compound and the cyanometallate compound, hybrid particles having both an M¹ _(b) [M²(CN)_(r)(X¹)_(t)]_(c) phase and an M³ metal or semi-metal oxide phase.

It is preferred to treat the precipitated catalyst with a complexing agent. This is conveniently done by washing the precipitated catalyst one or more times with a complexing agent or solution of the complexing agent in water. The complexing agent component may include at least one of an alcohol as described before with regard to the starting solution, a polyether, a polyester, a polycarbonate, a glycidyl ether, a glycoside, a polyhydric alcohol carboxylate, a polyalkylene glycol sorbitan ester, a bile acid or salt, a carboxylic acid ester or amide thereof, cyclodextrin, an organic phosphate, a phosphite, a phosphonate, a phosphonite, a phosphinate, a phosphinite, an ionic surface- or interface-active compound, and/or an α,β-unsaturated carboxylic acid ester. In exemplary embodiments, the organic complex agent is one or more of n-propanol, iso-propanol, n-butanol, sec-butanol, t-butanol, other alkylene monoalcohol having up to, for example, 12 carbon atoms, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, or other polyether having one or more hydroxyl groups and a molecular weight of up to, for example, 8000 g/mol.

The catalyst complex so made is conveniently recovered from the starting solution or any wash liquid, dried and, if desired, ground or milled to reduce the catalyst complex to a powder having a volume average particle size of, for example, 100 μm or smaller. Drying can be performed by heating and/or applying vacuum.

The M¹ metal compound preferably is water-soluble. It is typically a salt of an M¹ metal and one or more anions. Such a salt may have the formula M¹ _(x)A¹ _(y), wherein x, A1 and y are as described before. Suitable anions A¹ include, but are not limited to, halides such as chloride, bromide and iodide, nitrate, sulfate, carbonate, cyanide, oxalate, thiocyanate, isocyanate, perchlorate, isothiocyanate, an alkanesulfonate such as methanesulfonate, an arylenesulfonate such as p-toluenesulfonate, trifluoromethanesulfonate (triflate), and a C₁₋₄ carboxylate. In exemplary embodiments, the anion A¹ is not any of alkoxide, aryloxy, carboxylate, acyl, pyrophosphate, phosphate, thiophosphate, dithiophosphate, phosphate ester, thiophosphate ester, amide, oxide, siloxide, hydride, carbamate or hydrocarbon anion. The M¹ metal is one or more of Zn²⁺, Fe²⁺, Co⁺²⁺, Ni²⁺, Mo⁴⁺, Mo⁶⁺, Al⁺³⁺, V⁴⁺, V⁵⁺, Sr²⁺, W⁴⁺, W⁶⁺, Mn²⁺, Sn²⁺, Sn⁴⁺, Pb²⁺, Cu²⁺, La³⁺ and Cr³⁺. Zn²⁺ is the preferred M¹ metal. ZnCl₂ is a preferred M¹ metal compound.

The cyanometallate compound includes an M²(CN)_(r)(X¹)_(t) anion, where r, X¹ and t are as described before. r is preferably 6 and t is preferably zero. The M² metal is one or more of Fe³⁺, Fe²⁺, Co³⁺, Co²⁺, Cr²⁺, Cr³⁺, Mn²⁺, Mn³⁺, Ir³⁺, Ni²⁺, Rh³⁺, Ru²⁺, V⁴⁺, V⁵⁺, Ni²⁺, Pd²⁺, and Pt²⁺. The M² metal preferably is Fe³⁺ or Co³⁺, with Co³⁺ being especially preferred. The cyanometallate compound preferably is an alkali metal or ammonium salt, although the corresponding cyanometallitic acid can be used. Potassium hexacyanocobaltate is a particularly preferred cyanometallate compound.

The M³ metal or semi-metal compound is a compound of a metal or semi-metal M³ that falls within any of Groups 3 through 15, inclusive, of the 2010 IUPAC periodic table of the elements, and one or more anions. The metal may be, e.g., scandium, yttrium, lanthanum, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, titanium, silicon, palladium, platinum, copper, silver, gold, zinc, cadmium, mercury, aluminum, gallium, indium, tellurium, tin, lead, bismuth, and the lanthanide series metals including those having atomic numbers from 58 (cerium) to 71 (lutetium), inclusive.

Preferred M³ metals and semi-metals include yttrium, zirconium, nobium, silicon, titanium, tungsten, cobalt, scandium, vanadium, molybdenum, nickel, zinc and tin. More preferred are hafnium, aluminum, manganese, gallium and indium.

The anion of the M³ metal or semi-metal compound may be for example, one or more of alkoxide, aryloxy, carboxylate, acyl, pyrophosphate, phosphate, thiophosphate, dithiophosphate, phosphate ester, thiophosphate ester, amide, oxide, siloxide, hydride, carbamate, and/or hydrocarbon anion. Exemplary embodiments include the oxide, hydrocarbyl, oxide and/or the alkoxide ions. The anion is not a halide anion or a cyanide anion.

The M³ metal or semi-metal compound may be insoluble in the solvent or, if soluble, may react during the preparation of the catalyst complex to form an insoluble reaction product that becomes part of the catalyst complex. The M³ metal or semi-metal also preferably does not reduce a cyanometallate group or prevent the M¹ metal compound and cyanometallate compound from reacting to form an M¹ metal cyanometallate.

By “alkoxide” ion it is meant a species having the form ⁻O—R, where R is an alkyl group or substituted alkyl group, and which is the conjugate base, after removal of a hydroxyl hydrogen, of an alcohol compound having the form HO—R. These alcohols may have pKa values in the range of 13 to 25 or greater. The alkoxide ion in some embodiments may contain from 1 to 20 (e.g., from 1 to 6 and/or from 2 to 6) carbon atoms. The alkyl group or substituted alkyl group may be linear, branched, and/or cyclic. Examples of suitable substituents include, e.g., additional hydroxyl groups (which may be in the alkoxide form), ether groups, carbonyl groups, ester groups, urethane groups, carbonate groups, silyl groups, aromatic groups such as phenyl and alkyl-substituted phenyl, and halogens. Examples of such alkoxide ions include methoxide, ethoxide, isopropoxide, n-propoxide, n-butoxide, sec-butoxide, t-butoxide, and benzyloxy. The R group may contain one or more hydroxyl groups and/or may contain one or more ether linkages. An alkoxide ion may correspond to the residue (after removal of one or more hydroxyl hydrogens) of an starter compound that is present in the polymerization, such as those starter compounds described below. The alkoxide ion may be an alkoxide formed by removing one or more hydroxyl hydrogens from a polyether monol or polyether polyol; such an alkoxide in some embodiments corresponds to a residue, after removal of one or more hydroxyl hydrogen atoms, of the polyether monol or polyether polyol product that is obtained from the alkoxylation reaction, or of a polyether having a molecular weight intermediate to that of the starter compound and the product of the alkoxylation reaction.

By “aryloxy” anion it is meant a species having the form ⁻O—Ar, where Ar is an aromatic group or substituted group, and which corresponds, after removal of a hydroxyl hydrogen, to a phenolic compound having the form HO—Ar. These phenolic compounds may have a pKa of, e.g., from about 9 to about 12. Examples of such aryloxy anions include phenoxide and ring-substituted phenoxides, wherein the ring-substituents include, e.g., alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, and alkoxyl. The ring-substituent(s), if present, may be in one or more of the ortho-, para- and/or meta-positions relative to the phenolic group. The phenoxide anions also include the conjugate bases of polyphenolic compounds such as bisphenol A, bisphenol F and various other bisphenols, 1,1,1-tris(hydroxyphenyl)ethane, and fused ring aromatics such as 1-naphthol.

By “carboxylate” anion it is meant a carboxylate that contains from 1 to 24 (e.g., from 2 to 18 and/or from 2 to 12) carbon atoms. The carboxylate may be aliphatic or aromatic. An aliphatic carboxylic acid may contain substituent groups. Examples of such include hydroxyl groups (which may be in the alkoxide form), ether groups, carbonyl groups, ester groups, urethane groups, carbonate groups, silyl groups, aromatic groups such as phenyl and alkyl-substituted phenyl, and halogens. Examples of aliphatic carboxylate anions include formate, acetate, propionate, butyrate, 2-ethylhexanoate, n-octoate, decanoate, laurate and other alkanoates and halogen-substituted alkanoates such as 2,2,2-trifluoroacetate, 2-fluoroacetate, 2,2-difluoroacetate, 2-chloroacetate, and 2,2,2-trichloroacetate. Examples of aromatic carboxylates include benzoate, alkyl-substituted benzoate, halo-substituted benzoate, 4-cyanobenzoate, 4-trifluoromethylbenzoate, salicylate, 3,5-di-t-butylsalicylate, and subsalicylate. In some embodiments, such a carboxylate ion may be the conjugate base of a carboxylic acid having a pKa from 1 to 6 (e.g., from 3 to 5).

By “acyl” anion it is meant a conjugate base of a compound containing a carbonyl group including, e.g., an aldehyde, ketone, acetylacetonate, carbonate, ester or similar compound that has an enol form. Examples of these are ß-diketo compounds, such as acetoacetonate and butylacetoacetonate.

By “phosphate” anion it is meant a phosphate anion that have the formula —O—P(O)(OR₁)₂, wherein R₁ is alkyl, substituted alkyl, phenyl, or substituted phenyl. By “thiophosphate” anion it is meant thiophosphate anions have the corresponding structure in which one or more of the oxygens are replaced with sulfur. The phosphate and thiophosphates may be ester anions, such as phosphate ester and thiophosphate ester.

By “pyrophosphate” anion it is meant the P₂O₇ ⁴⁻ anion.

By “amide” anion it is meant an ion in which a nitrogen atom bears a negative charge. The amide ion generally takes the form —N(R₂)₂, wherein the R₂ groups are independently hydrogen, alkyl, aryl, trialkylsilyl, or triarylsilyl. The alkyl groups may be linear, branched, or cyclic. Any of these groups may contain substituents such as ether or hydroxyl. The two R₂ groups may together form a ring structure, which ring structure may be unsaturated and/or contain one or more heteroatoms (in addition to the amide nitrogen) in the ring.

By “oxide” anion is meant the anion of atomic oxygen, i.e., O²⁻.

By “siloxide” anion it is meant silanoates having the formula (R₃)₃SiO⁻, wherein R₃ groups are independently hydrogen or alkyl group.

By “hydride” anion it is meant the anion of hydrogen, i.e., H—

By “carbamate” anion it is meant the anion —OOCNH₂.

By “hydrocarbon” anion it is meant hydrocarbyl anions that include aliphatic, cycloaliphatic and/or aromatic anions wherein the negative charge resides on a carbon atom. The hydrocarbyl anions are conjugate bases of hydrocarbons that typically have pKa values in excess of 30. The hydrocarbyl anions may also contain inert substituents. Of the aromatic hydrocarbyl anions, phenyl groups and substituted phenyl groups may be used. Aliphatic hydrocarbyl anions may be alkyl groups, e.g., which contain from 1 to 12 (e.g., from 2 to 8) carbon atoms. For example, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, cyclopentadienyl and t-butyl anions are all useful.

Examples of compounds for use in the additive compound include but are not limited to:

a) magnesium alkyls such as diethyl magnesium, dibutyl magnesium, butylethyl magnesium, dibenzyl magnesium and the like; magnesium alkoxides such as magnesium methoxide, magnesium ethoxide, magnesium isopropoxide, magnesium t-butoxide, magnesium sec-butoxide and the like; magnesium aryloxides such as magnesium phenoxide, and magnesium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; magnesium carboxylates such as magnesium formate, magnesium acetate, magnesium propionate, magnesium 2-ethylhexanoate, magnesium benzoate, magnesium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, magnesium salicylate, magnesium 3,5-di-t-butyl salicylate; magnesium amides such as magnesium dimethylamide, magnesium diethylamide, magnesium diphenylamide, magnesium bis(trimethylsilyl)amide and the like; magnesium oxide, magnesium acetylacetonate and magnesium t-butylacetylacetonate;

b) scandium alkoxides such as scandium methoxide, scandium ethoxide, scandium isopropoxide, scandium t-butoxide, scandium sec-butoxide and the like; scandium oxide; scandium aryloxides such as scandium phenoxide and scandium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; scandium carboxylates such as scandium formate, scandium acetate, scandium propionate, scandium 2-ethylhexanoate, scandium benzoate, scandium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; scandium salicylate; scandium acetylacetonate and scandium t-butylacetylacetonate;

c) yttrium alkoxides such as yttrium methoxide, yttrium ethoxide, yttrium isopropoxide, yttrium t-butoxide, yttrium sec-butoxide and the like; yttrium oxide; yttrium aryloxides such as yttrium phenoxide, and yttrium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; yttrium carboxylates such as yttrium formate, yttrium acetate, yttrium propionate, yttrium 2-ethylhexanoate, yttrium benzoate, yttrium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, yttrium salicylate, yttrium 3,5-di-t-butyl salicylate; yttrium amides such as yttrium dimethylamide, yttrium diethylamide, yttrium diphenylamide, yttrium bis(trimethylsilyl)amide and the like; yttrium acetylacetonate and yttrium t-butylacetylacetonate;

d) hafnium alkyls such as such as tetraethyl hafnium, tetrabutyl hafnium, tetrabenzyl hafnium and the like; hafnium oxide; hafnium alkoxides such as hafnium tetramethoxide, hafnium tetraethoxide, hafnium tetraisopropoxide, hafnium tetra-t-butoxide, hafnium tetra-sec-butoxide and the like; hafnium aryloxides such as hafnium phenoxide and hafnium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; hafnium carboxylates such as hafnium formate, hafnium acetate, hafnium propionate, hafnium 2-ethylhexanoate, hafnium benzoate, hafnium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, hafnium salicylate, hafnium 3,5-di-t-butyl salicylate; hafnium amides such as hafnium tetra(dimethylamide), hafnium tetra(diethylamide), hafnium tetra(diphenylamide), hafnium tetra((bistrimethylsilyl)amide); hafnium acetylacetonate and hafnium t-butylacetylacetonate;

e) zirconium alkyls such as such as tetraethyl zirconium, tetrabutyl zirconium, tetrabenzyl zirconium and the like; zirconium oxide; zirconium alkoxides such as zirconium tetramethoxide, zirconium tetraethoxide, zirconium tetraisopropoxide, zirconium tetra-t-butoxide, zirconium tetra-sec-butoxide and the like; zirconium aryloxides such as zirconium phenoxide and zirconium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; zirconium carboxylates such as zirconium formate, zirconium acetate, zirconium propionate, zirconium 2-ethylhexanoate, zirconium benzoate, zirconium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, zirconium salicylate, zirconium 3,5-di-t-butyl salicylate; zirconium amides such as zirconium tetra(dimethylamide), zirconium tetra(diethylamide, zirconium tetra(diphenylamide), zirconium tetra((bistrimethylsilyl)amide); zirconium acetylacetonate and zirconium t-butylacetylacetonate;

f) vanadium alkoxides such as vanadium methoxide, vanadium ethoxide, vanadium isopropoxide, vanadium t-butoxide, vanadium sec-butoxide and the like; vanadium oxide; vanadium oxo tris(alkoxides) such as vanadium oxo tris(methoxide), vanadium oxo tris(ethoxide), vanadium oxo tris(isopropoxide), vanadium oxo tris(t-butoxide), vanadium oxo tris(sec-butoxide) and the like; vanadium aryloxides such as vanadium phenoxide and vanadium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; vanadium carboxylates such as vanadium formate, vanadium acetate, vanadium propionate, vanadium 2-ethylhexanoate, vanadium benzoate, vanadium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, vanadium salicylate, vanadium 3,5-di-t-butyl salicylate; vanadium tris(acetylacetonate) and vanadium tris(t-butylacetylacetonate); vanadium oxo bis(acetylacetonate);

g) zinc alkyls such as such as dimethyl zinc, diethyl zinc, dibutyl zinc, dibenzyl zinc and the like; zinc oxide; alkyl zinc alkoxides such as ethyl zinc isopropoxide; zinc alkoxides such as zinc methoxide, zinc ethoxide, zinc isopropoxide, zinc t-butoxide, zinc sec-butoxide and the like; zinc aryloxides such as zinc phenoxide and zinc phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; zinc carboxylates such as zinc formate, zinc acetate, zinc propionate, zinc 2-ethylhexanoate, zinc benzoate, zinc benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, zinc salicylate, zinc 3,5-di-t-butyl salicylate; zinc amides such as zinc dimethylamide, zinc diethylamide, zinc diphenylamide, zinc (bistrimethylsilyl)amide; zinc acetylacetonate and zinc t-butylacetylacetonate;

h) trialkyl aluminum compounds such as trimethylaluminum, triethyl aluminum, tributyl aluminum, tribenzylaluminum and the like; aluminum alkoxides such as aluminum trimethoxide, aluminum triethoxide, aluminum triisopropoxide, aluminum tri-t-butoxide, aluminum tri-sec-butoxide and the like; aluminum aryloxides such as aluminum phenoxide and aluminum phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; aluminum oxide; aluminum carboxylates such as aluminum formate, aluminum acetate, aluminum propionate, aluminum 2-ethylhexanoate, aluminum benzoate, aluminum benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, aluminum salicylate, aluminum 3,5-di-t-butyl salicylate; aluminum amides such as aluminum tris(dimethylamide), aluminum tris(diethylamide), aluminum tris(diphenylamide), aluminum tris(di(trimethylsilyl)amide) and the like; aluminum acetylacetonate; aluminum t-butylacetylacetonate; and alkylaluminum oxides and alkoxides such as diethylaluminum ethoxide, dimethylaluminum ethoxide, diethylaluminum isopropoxide, dimethylaluminum isopropoxide, methyl aluminoxane, tetraethyldialuminoxane and the like;

i) trialkyl gallium compounds such as trimethylgallium, triethyl gallium, tributyl gallium, tribenzylgallium and the like; gallium oxide; gallium alkoxides such as gallium trimethoxide, gallium triethoxide, gallium triisopropoxide, gallium tri-t-butoxide, gallium tri-sec-butoxide and the like; gallium aryloxides such as gallium phenoxide and gallium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; gallium carboxylates such as gallium formate, gallium acetate, gallium propionate, gallium 2-ethylhexanoate, gallium benzoate, gallium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, gallium salicylate, gallium 3,5-di-t-butyl salicylate; gallium amides such as gallium tris(dimethylamide), gallium tris(diethylamide), gallium tris(diphenylamide), gallium tris(di(trimethylsilyl)amide) and the like; gallium acetylacetonate; gallium t-butylacetylacetonate; and alkylgallium alkoxides such as diethylgallium ethoxide, dimethylgallium ethoxide, diethylgallium isopropoxide and dimethylgallium isopropoxide;

j) trialkyl indium compounds like trimethyl indium; indium oxide; indium alkoxides such as indium methoxide, indium ethoxide, indium isopropoxide, indium t-butoxide, indium sec-butoxide and the like; indium aryloxides such as indium phenoxide and indium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; indium carboxylates such as indium formate, indium acetate, indium propionate, indium 2-ethylhexanoate, indium benzoate, indium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, indium salicylate, indium 3,5-di-t-butyl salicylate; indium acetylacetonate; and indium t-butylacetylacetonate;

k) stannous phosphate; stannous pyrophosphate, stannous oxide; stannic oxide; stannous alkoxides such as stannous methoxide, stannous ethoxide, stannous isopropoxide, stannous t-butoxide, stannous sec-butoxide and the like; stannous aryloxides such as stannous phenoxide and stannous phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; stannous carboxylates such as stannous formate, stannous acetate, stannous propionate, stannous 2-ethylhexanoate, stannous benzoate, stannous benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, stannous salicylate, stannous 3,5-di-t-butyl salicylate; stannous acetylacetonate; and stannous t-butylacetylacetonate;

l) manganese phosphate; pyrophosphate, manganese oxide; manganese alkoxides such as manganese methoxide, manganese ethoxide, manganese isopropoxide, manganese t-butoxide, manganese sec-butoxide and the like; manganese aryloxides such as manganese phenoxide and manganese phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; manganese carboxylates such as manganese formate, manganese acetate, manganese propionate, manganese 2-ethylhexanoate, manganese benzoate, manganese benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, manganese salicylate, manganese 3,5-di-t-butyl salicylate; manganese acetylacetonate; and manganese t-butylacetylacetonate;

m) molybdenum compounds, including Mo(IV) and/or Mo(VI) compounds such as molybdenum phosphate; molybdenum pyrophosphate, molybdenum oxide; molybdenum alkoxides such as molybdenum methoxide, molybdenum ethoxide, molybdenum isopropoxide, molybdenum t-butoxide, molybdenum sec-butoxide and the like; molybdenum aryloxides such as molybdenum phenoxide and molybdenum phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; molybdenum carboxylates such as molybdenum formate, molybdenum acetate, molybdenum propionate, molybdenum 2-ethylhexanoate, molybdenum benzoate, molybdenum benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, molybdenum salicylate, molybdenum 3,5-di-t-butyl salicylate; molybdenum acetylacetonate; and molybdenum t-butylacetylacetonate; in each case being an Mo(IV) or (MoVI) compound;

m) cobalt (II) and/or Co(III) compounds such as cobalt phosphate; cobalt pyrophosphate, cobalt oxide; cobalt alkoxides such as cobalt methoxide, cobalt ethoxide, cobalt isopropoxide, cobalt t-butoxide, cobalt sec-butoxide and the like; cobalt aryloxides such as cobalt phenoxide and cobalt phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; cobalt carboxylates such as cobalt formate, cobalt acetate, cobalt propionate, cobalt 2-ethylhexanoate, cobalt benzoate, cobalt benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, cobalt salicylate, cobalt 3,5-di-t-butyl salicylate; cobalt acetylacetonate; and cobalt t-butylacetylacetonate, in each case being a Co(II) and/or Co(III) compound;

o) tungsten compounds such as tungsten phosphate; tungsten pyrophosphate, tungsten oxide; tungsten alkoxides such as tungsten methoxide, tungsten ethoxide, tungsten isopropoxide, tungsten t-butoxide, tungsten sec-butoxide and the like; tungsten aryloxides such as tungsten phenoxide and tungsten phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; tungsten carboxylates such as tungsten formate, tungsten acetate, tungsten propionate, tungsten 2-ethylhexanoate, tungsten benzoate, tungsten benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, tungsten salicylate, tungsten 3,5-di-t-butyl salicylate; tungsten acetylacetonate; and tungsten t-butylacetylacetonate;

p) iron (II) and/or iron (III) compounds such as iron phosphate; iron pyrophosphate, iron oxide; iron alkoxides such as iron methoxide, iron ethoxide, iron isopropoxide, iron t-butoxide, iron sec-butoxide and the like; iron aryloxides such as iron phenoxide and iron phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; iron carboxylates such as iron formate, iron acetate, iron propionate, iron 2-ethylhexanoate, iron benzoate, iron benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, iron salicylate, iron 3,5-di-t-butyl salicylate; iron acetylacetonate; and iron t-butylacetylacetonate, in each case being a Fe(II) and/or Fe(III) compound;

q) titanium compounds such as titanium phosphate; titanium pyrophosphate, titanium oxide; titanium alkoxides such as titanium methoxide, titanium ethoxide, titanium isopropoxide, titanium t-butoxide, titanium sec-butoxide and the like; titanium aryloxides such as titanium phenoxide and titanium phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like; titanium carboxylates such as titanium formate, titanium acetate, titanium propionate, titanium 2-ethylhexanoate, titanium benzoate, titanium benzoates in which one or more of the benzoate groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like, titanium salicylate, titanium 3,5-di-t-butyl salicylate; titanium acetylacetonate; and titanium t-butylacetylacetonate; and

r) silicon compounds such as silicon oxide and silicon alkoxides such as silicon methoxide, silicon tetra ethoxide, silicon tetra isopropoxide, silicon tetra-t-butoxide, silicon tetra sec-butoxide and the like; silicon aryloxides such as silicon tetra phenoxide and silicon tetra phenoxides in which one or more of the phenoxide groups is ring-substituted with alkyl, CF₃, cyano, COCH₃, halogen, hydroxyl, alkoxyl and the like.

The catalyst complex (including those prepared in the process described above) in some embodiments of the invention corresponds to the formula: M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(c)[M⁵(X²)₆]_(d) ·nM⁴ _(x)A¹ _(y) ·pM³ _(w)A² _(z) wherein the variables are as described before. M¹ and M⁴ each most preferably are zinc. M² and M⁵ each most preferably are iron and cobalt, especially cobalt. M³ and A² preferably are as described above with regard to the M³ metal or semi-metal compound. r is most preferably 6 and t is most preferably zero. d is most preferably 0-1. The mole ratio of M¹ and M⁴ metals combined to M² and M⁵ metals combined is preferably 0.8:1 to 20:1. The mole ratio of M³ metal or semi-metal to M² and M⁵ metals combined may be, for example, 0.002 to 10 as determined by X-ray fluorescence (XRF) methods. It is noted that the ratios of metals in the catalyst complex may differ substantially from the ratios employed in the catalyst preparation process.

The formula in the foregoing process is not intended to denote any special crystalline form or other spatial or chemical relationship between the M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(e)[M⁵(X²)₆]_(d), M⁴ _(x)A¹ _(y) and M³ _(w) A² _(z) components of the catalyst complex. Scanning transmission electron spectroscopy of certain catalyst complexes has revealed that at least some of in such embodiments the catalyst complex comprises hybrid particles having both an M¹ _(b)[M²(CN(X¹)_(t)]_(c) phase and an M³ metal or semi-metal oxide (i.e., M³ _(w)O_(z) phase). The M⁴ _(x)A¹ _(y) phase, when present, is believed to reside at least partially on particles of the M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(c) phase. In addition to such hybrid particles, the catalyst complex may contain particles of the M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(c) phase or of a M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(c)[M⁵(X²)₆]_(d)·nM⁴ _(x)A¹ _(y) phase only, and other particles of the M⁴ _(x)A¹ _(y) phase only. Some of the M³ metal or semi-metal may become incorporated into the M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(c) phase or into a M¹ _(b)[M²(CN)_(r)(X¹)_(t)]_(c)[M⁵(X²)₆]_(d)·nM⁴ _(x)A¹ _(y) phase.

In certain embodiments, the catalyst complex comprises a physical admixture of particles of a water-insoluble zinc hexacyanocobaltate with particles of an M³ metal or semi-metal oxide, the M³ metal or semi-metal oxide particles being present in an amount to provide 0.002 to 10 moles of M³ metal or semi-metal per mole of cobalt provided by the zinc hexacyancobaltate, and further wherein the M³ metal or semi-metal oxide particles have a surface area of at least 1 m²/g as measured using gas sorption methods. The surface area of the M³ metal or semi-metal oxide particles may be at least 10 m²/g or at least 100 m²/g, and may be up to, for example, 300 m³/g or more. Their volume average particle size may be 100 am or smaller, 25 am or smaller, 1 μm or smaller or 500 nm or smaller. Such physical admixtures can be made by, for example, forming solid particles of the zinc hexacyanocobaltate and combining them with the M³ metal or semi-metal oxide particles. This can be done at any stage of the zinc hexacyanocobaltate preparation process after the zinc hexacyanocobaltate has precipitated. For example, it is common to wash a precipitated zinc hexacyanocobaltate with water and/or a ligand one or more times before final drying. The M³ metal or semi-metal oxide can be combined with the zinc hexacyanocobaltate during any such washing step.

Polyethers made in accordance with the invention may include monoalcohols such as are useful for surfactant and industrial solvent or lubricant applications, and polyols such as are useful raw materials for producing polymers such as polyurethanes such as molded foams, slabstock foams, high resiliency foams, viscoelastic foams, rigid foams, adhesives, sealants, coatings, elastomers, composites, etc.

The following examples are provided to illustrate exemplary embodiments and are not intended to limit the scope thereof. All parts and percentages are by weight unless otherwise indicated.

EXAMPLES 1-4 AND COMPARATIVE SAMPLES A-C

To make Example 1: A mixture of zinc chloride (16.00 grams, 117.4 mmol), tert-butyl alcohol (20 mL), and deionized water (20 mL) is heated to 40° C. in a round-bottomed flask. Subsequently, aluminum sec-butoxide (in an amount as indicated in Table 1) and aqueous HCl (48 μL, 0.001 M) are added to the flask and the mixture is stirred for 10 minutes are ambient conditions. Next, a solution of potassium hexacyanocobaltate (3.44 grams, 10.4 mmol) premixed with water (40 mL) is added dropwise over a period of 2.5 hours. The mixture in the flask then is heated under reflux until a white gel forms after a period of approximately 20 hours. The resultant gel is dispersed in water (60 mL) and tert-butyl alcohol (60 mL) and centrifuged (5000 rpm) for a period of 15 minutes. The solvent is decanted and the resultant material is again dispersed in a mixture of water (60 mL) and tert-butyl alcohol (60 mL). The resultant dispersion is heated to 55° C. for 35 minutes and then centrifuged (5000 rpm) for a period of 15 minutes. The resultant material is then washed four times with 50/50 by volume mixture of distilled water and tert-butyl alcohol and once more using tert-butyl alcohol (120 mL). The washed material is dried under vacuum at 70° C. overnight to a constant pressure (<10 mbar). The resultant dried solid is milled, forming a catalyst sample in the form of a finely divided powder.

Examples 2-4 and Comparative Samples A and B are made in the same way except the amount of aluminum sec-butoxide added into the preparation is varied. The aluminum sec-butoxide is eliminated altogether in making Comparative Sample C. The mole ratios of cobalt:zinc:aluminum added into the catalyst preparation for these various samples are as indicated in Table 1. The mole ratios of cobalt:zinc:aluminum in the process are determined by XRF, with results as indicated in Table 1.

TABLE 1 Aluminum Co:Zn:Al Co:Zn:Al sec-butoxide, mole ratio, mole ratio, Designation g (mmol) prep product A* 0.0084 g, 0.034 mmol 1:11.3:0.003 1:2:<0.001 1  0.084 g, 0.340 mmol 1:11.3:0.032 1:2:0.003 2 0.83 g, 3.4 mmol 1:11.3:0.32 l:2.0:0.2 3  8.27 g, 33.6 mmol 1:11.3:3.2 1:2.2:2.8 4 16.55 g, 67.2 mmol 1:11.3:6.4 1:2.8:5.2 B* 82.74 g, 336 mmol  1:11.3:32 1:8.5:32 C* None 1:11.3:0 1:2:0

Catalyst Examples 1-4 and Comparative Samples A, B and C are used to produce polyether polyols in a semi-batch process. Dipropylene glycol (475.4 g) and 142.0 milligrams of the catalyst sample (enough to provide 100 parts per million based on the expected mass of the product) are added a 7 L Juchheim reactor at 60° C. and stirred at 50 rpm under dry nitrogen. The reactor is closed and set to 100° C. and 400 rpm. Then, the atmosphere within the reactor is purged with dry nitrogen and vacuum is applied. This part of the procedure is repeated four additional times. The reactor is isolated and placed under vacuum for one hour at 160° C. to dry the starting materials. 140 g of propylene oxide are then added to the reactor at the same temperature. This raises the internal reactor pressure to about 3 bar gauge (304 kPa) (all pressures reported herein are gauge pressures unless noted otherwise). The pressure inside the reactor is continuously monitored for a pressure drop that indicates catalyst activation has taken place. The time required for the reactor pressure to drop to 1 bar (101 kPa) is noted as the activation time. 40 minutes after the start of the process (or upon catalyst activation in cases in which the catalyst has not yet activated after 40 minutes), 868.8 g of propylene oxide is fed to the reaction at 160° C. The feed rate is increased linearly from zero to 29 g/min over the course of one hour unless the internal pressure during the feed reaches 4 bar (405 kPa), in which case the feed rate is discontinued until the pressure drops to 3.5 bar (354 kPa), at which point the feed is resumed. Therefore, the shortest possible time for the propylene oxide addition is 60 minutes, which can be obtained only if the reactor pressure does not reach the pressure limit during the propylene oxide feed. After the propylene oxide is completed, the reaction mixture is digested for 15 minutes at 160° C. Vacuum is then is applied to remove any unreacted propylene oxide. The reactor is then cooled to 100° C. and 200 ppm of an antioxidant is added to the reaction mixture under dry nitrogen. Then, the product is cooled to ambient temperature and collected. Batch size is approximately 1421.8 grams in each case. The product molecular weight is 400 g/mol. During the polymerization, the hydroxyl content of the reaction mixture decreases from about 20% by weight to about 4.25% by weight.

The internal reactor pressure is monitored during the reaction as in indication of the activity of the catalyst. These polymerization conditions represent a difficult challenge for conventional double metal cyanide catalysts because of the low molecular weight of the starter (dipropylene glycol). Conventional DMC catalysts perform poorly in the presence of high concentrations of hydroxyl groups, which is the case during early stages of a semi-batch process such as this in which the starter molecular weight is low. It is for this reason that the propylene oxide feed rate is ramped up gradually after catalyst activation. The catalyst activity and therefore polymerization rate is expected to increase as the product builds molecular weight, which allows the propylene oxide to be consumed more rapidly and therefore be fed more rapidly.

FIG. 1 is a plot (line 1) of reactor pressure vs. time for Comparative Sample C and of propylene oxide feed rate vs. time (line 21). Section 2 of line 1 represents the increase in reactor pressure during the initial propylene oxide feed. The pressure increases to about 3 bar (303 kPa). The following slow decrease in reactor pressure indicated in section 3 of line 1 indicates the consumption of propylene oxide as the catalyst activates. The time at which the pressure decreases to 1 bar (101 kPa) is indicated by point A, which is at about 55 minutes after the start of the process. Point A is taken as the catalyst activation time. Segment 4 of line 1 indicates the increase in pressure as the subsequent propylene oxide feed is commenced. As shown in FIG. 1 , the reactor pressure reaches the 4 bar (405 kPa) pressure limit in 30-40 minutes. During that time, the propylene oxide feed rate reaches as high as 10 g/minute but must be discontinued or slowed periodically when the reactor pressure limit is reached.

Segment 5 of line 1 indicates that the activity of the catalyst remains very low for a period extending to approximately 200 minutes from the start of the process. During almost all of this time it is only possible to feed propylene oxide at a low feed rate of 2-7 g/minute during the corresponding time period (as shown by line 21); higher feed rates would cause the internal pressure limit to be exceeded. It is only after 180-190 minutes that the catalyst activity increases substantially, which allows the propylene oxide feed rate to be increased to 25-30 g/minute. At this point, reactor pressure falls substantially despite the rapid feed rate, as indicated by segment 6 of line 1. At this point of the reaction, propylene oxide is being consumed at rates greater than 30 g/minute. The entire amount of propylene oxide fed (868.6 grams) is consumed 210-220 minutes after the start of the process. Segment 7 of line 1 indicates the reactor pressure during the final digestion step after all propylene oxide has been fed to the reactor.

FIG. 1 demonstrates the severity of these polymerization conditions. The starter has a low equivalent weight and is present in high concentrations at the start of the reaction until a significant amount of molecular weight has been attained. The hydroxyl content is high throughout the entire polymerization process. These conditions make it difficult for the catalyst to even activate, and when the catalyst is activated, these conditions cause it to perform sluggishly during most of the course of the polymerization. This is despite using a rather large concentration of catalyst.

Comparative Sample A exhibits a similar pressure curve as Comparative Sample C. Catalyst activation requires 65-70 minutes. The propylene oxide feed rate is restricted to no more than 5 g/minute until about 180 minutes after the start of the process, at which point rapid polymerization in excess of 30 g of propylene oxide per minute commences. The addition of the very small amount of aluminum into the catalyst has virtually no effect on catalyst performance.

FIG. 2 shows the corresponding pressure vs. time (line 1) and propylene oxide vs. time (line 21) plots for Example 1. The reference numerals refer to the same features as do the corresponding numerals in FIG. 1 . Catalyst activation is very rapid in this example, as indicated by segment 3 of line 1. Reactor pressure falls to 1 bar (101 kPa) only 10-15 minutes after starting the process, and continues to fall to below 0.5 bar (50 kPa) before the propylene oxide feed begins. Segment 4 of line 1 shows the pressure rise as the propylene oxide feed is started. The pressure rises to 3.5-3.7 bar (355-376 kPa) as the propylene oxide feed rate increases to 15-20 g/minute. Note that the internal pressure limit is never reached despite the much faster ramping of the propylene oxide feed rate than occurred in Comparative Sample C. The peak pressure is attained after only about 70 minutes. Thereafter, the reactor pressure decreases rapidly (segment 6 of line 1) despite the further increase in propylene oxide feed rate, due to the rapid polymerization of the propylene oxide. All of the propylene oxide is fed within 100 minutes of the start of the process. Note that there is no segment of line 1 that corresponds to segment 5 in FIG. 1 . With Catalyst Example 1, there is no need to restrict the propylene oxide feed rate to avoid reaching the internal reactor limit. These excellent results are attained despite the very severe conditions of this test. In fact, even faster polymerizations can be obtained using this catalyst under these conditions, by increasing the rate of the propylene oxide feed. These data also suggest that lower catalyst concentrations can be used even under these severe conditions.

The activation time, time to rapid polymerization and time to complete the propylene feed for each of Examples 1-4 and Comparative Samples A-C are as indicated in Table 2:

TABLE 2 Co:Zn:Al Activation Onset of Rapid Time to mole ratio, Time, Polymerization, Complete PO Designation product min min feed, min A* 1:2:0.001 65-70 180 210-220 1 1:2:0.003 10-15 70 100**  2 1:2.0:0.2  5-10 65-70 100**  3 1:2.2:2.8  5-10 70 100**  4 1:2.8:5.2 40 90 105    B* 1:8.5:32 125 >300 >500¹     C* 1:2:0 55 180-190 210-220 *Not an example of the invention. **Minimum feed time possible in this experiment; because the reactor pressure never reaches the pressure limit, faster propylene oxide feed rates could be used to obtain significantly shorter times to complete the PO feed. ¹Rapid onset of polymerization is never clearly seen.

As can be seen from the data in Table 2, the performance of conventional DMC catalyst (Comp. C) is characterized by a long activation time and long times until the onset of rapid polymerization and until all the propylene oxide can be fed. Comparative Sample A shows that the addition of very small amounts of the aluminum compound into the catalyst preparation does not materially affect catalyst performance.

However, Examples 1-4 demonstrate very significant increases in both the rate of catalyst activation and the polymerization rate when the amount of aluminum added into the catalyst is within a range of about 0.003 to about 5.2 moles per mole of cobalt (and especially within a range of 0.003 to about 3 moles Al/mole Co). Activation times decrease and polymerization rates increase dramatically.

Comparative Sample B demonstrates that increasing the amount of aluminum too much leads to a loss of catalytic activity, as though the presence of those large amounts of aluminum is acting as a catalyst poison.

EXAMPLES 5-11

Examples 5-11 are made in the same manner as Example 1, except the aluminum sec-butoxide in each case is replaced with 33.6 mmol of an M³ metal or semi-metal compound as set forth in Table 3. The mole ratio of Co:Zn:M³ metal or semi-metal in the prep and as measured in the catalyst product are indicated in Table 3. In each case, the catalyst is evaluated in a polyol production process as described with regard to the preceding examples. The activation time, time to onset of rapid polymerization and the time to complete the propylene oxide addition are as indicated in Table 3.

TABLE 3 Onset of Rapid Time to Co:Zn:M³ Co:Zn:M³ Acti- Poly- Com- mole mole vation meri- plete M3 ratio, ratio, Time, zation PO feed, Design. Compound prep product min min min Ex. 5  Hf (IV) 1:11.3:3   1:1.9:6.0 <10 70-75  100** isopropoxide Ex. 6  Ga (III) 1:11.3:3   1:2.0:4.7 <10 65  100** isopropoxide Ex. 7  In (III) 1:11.3:3   1:1.9:2.8 20 90  100** isopropoxide Ex. 8  Sc (III) oxide 1:11.3:3   1:1.8:6.2 40-50 125 130-140  Ex. 9  Mn(III) oxide 1:11.3:1.5 1:1.9:3.4 20 85 100 Ex. 10 Si(IV) 1:11.3:3.3 1:1.8:5.5 15-20 80-85 100-105¹ isopropoxide Ex. 11 Ti(IV) 1:11.3:3.3 1:2.0:3.3 15 85-90  100¹ isopropoxide **Minimum feed time possible in this experiment; because the reactor pressure never reaches the pressure limit, faster propylene oxide feed rates could be used to obtain significantly shorter times to complete the PO feed. ¹The reactor pressure reaches the upper pressure limit one or more times before rapid polymerization begins.

Each of Examples 5-11 exhibits a short activation time and/or shorter time to onset of rapid polymerization. Of particular note are the hafnium-, gallium-, and indium-modified catalysts, all of which not only provide short activation times, but also would permit an even faster propylene oxide feed rate than used in these experiments. In those three cases (as with Examples 1-4 above), the PO feed rate can be ramped up considerably faster than is done in these experiments, which would lead to even faster completion of the PO feed and shorter overall process cycle times.

EXAMPLES 12-14

Examples 12-14 are made in the same manner as Example 1, except the aluminum sec-butoxide in each case is replaced with 33.6 mmol of an M³ metal compound as set forth in Table 4 (only 16.8 mmol in the case of Comp. Sample F and 11.2 mmol in the case of Comp. Sample H). The mole ratio of Co:Zn:M³ metal in the prep and as measured in the catalyst product are indicated in Table 4.

In each case, the catalyst is evaluated in an alternative polyol production process which allows for estimates of activation time and time to onset of rapid PO polymerization.

Dipropylene glycol, (475.4 g) and enough of the catalyst sample (enough to provide 100 parts per million based on the expected mass of the product) are added a 7 L Juchheim reactor at 60° C. and stirred at 50 rpm under dry nitrogen. The reactor is closed and set to 100° C. with stirring. Then, the atmosphere within the reactor is purged with dry nitrogen one or more times. The reactor is then filled with nitrogen to atmospheric pressure (absolute). 77.4 g of propylene oxide are then added to the reactor at the same temperature. This raises the internal reactor pressure to about 3 bar gauge (305 kPa). The pressure inside the reactor is continuously monitored for a pressure drop that indicates catalyst activation has taken place. The time required for the reactor pressure to drop to 1-1.5 bar (101-151 kPa) is noted as the activation time. When the catalyst has activated, 868.8 g of propylene oxide is fed to the reaction at 160° C. The feed rate is increased linearly from zero to up 5 mL/minute over the course of one hour unless the internal pressure during the feed reaches 4.5 bar (456 kPa), in which case the feed rate is reduced until the pressure drops to 4 bar (405 kPa), at which point the feed rate is again increased. After the propylene oxide is completed, the reaction mixture is digested for 15 minutes at 160° C. Vacuum is then is applied to remove any unreacted propylene oxide. The reactor is then cooled to 100° C. and 200 ppm of an antioxidant is added to the reaction mixture under dry nitrogen. Then, the product is cooled to ambient temperature and collected. Batch size is approximately 1422 grams in each case.

FIG. 3 is a plot (line 11) of reactor pressure vs. time and of propylene oxide feed rate (line 21) for Example 14. Because the polymerization process for Examples 12-14 is performed under nitrogen (rather than under vacuum as in previous examples), the shape of the reactor pressure vs. time curve is somewhat different than described with regard to FIG. 1 . Section 12 of line 21 represents the increase in reactor pressure during the initial propylene oxide feed, during which the propylene oxide feed rate is 5 mL/min (segment 22 of line 21). The pressure increases to about 65 psig (448 kPa) during this step. The following slow decrease in reactor pressure indicated in section 13 of line 11 indicates the consumption of propylene oxide as the catalyst activates. The time at which the pressure decreases to 2 bar (202 kPa) is indicated by point A, which is at about 33 minutes after the start of the process. Point A is taken as the catalyst activation time. Segment 14 of line 11 indicates the increase in pressure as the subsequent propylene oxide feed is commenced. As shown by segment 14 of line 11, the reactor pressure increases approximately linearly as the propylene oxide feed rate is ramped step-wise from zero to 2 mL/min over a period of approximately 20 minutes, until the reactor pressure reaches the 4 bar (405 kPa) pressure limit about one hour after the start of the process (point B on line 11). During this period the rate at which propylene oxide is consumed is lower than the feed rate. The feed rate is therefore reduced to a rate that maintains a reactor pressure slightly below the reactor pressure limit; this period corresponds to segment 15 of line 11. During this period of about 20 minutes, the propylene oxide feed rate can be increased only slowly from 1 to 3 mL/min over about 30 minutes. Segment 15 of line 11 indicates that the activity of the catalyst remains sluggish for a period extending to approximately 90 minutes from the start of the process. The onset of rapid polymerization is indicated at point C of line 11, about 90 minutes after the start of the process. After this point, reactor pressure falls even as the propylene oxide feed rate is escalated rapidly to 5 mL/min, as indicated by segment 16 of line 11 (pressure) and segment 26 of line 21 (feed rate). At this point of the reaction and thereafter, propylene oxide is being consumed at rates greater than 5 mL/minute. Note that the reactor pressure indicated in FIG. 3 includes the nitrogen partial pressure, which at the start of the process is only 1 bar (101 kPa) but steadily increases as the reactor fills and the head space volume reduces. The reactor pressure reaches a constant value of about 25 psig (172 kPa) during the period indicated by segment 17 of line 11—this value is almost entirely due to the nitrogen partial pressure, the propylene oxide partial pressure at this point is close to zero. At this point the polymerization rate is such that propylene oxide could be fed a substantially higher rates if so desired. The entire amount of propylene oxide fed is consumed 110 minutes after the start of the process. Segment 18 of line 11 indicates the reactor pressure during the final digestion step after all propylene oxide has been fed to the reactor. This pressure during this stage of the process is almost entirely due to the presence of nitrogen in the headspace.

The activation time and time to onset of rapid polymerization are as indicated in Table 4.

TABLE 4 Onset of Co:Zn:M³ Co:Zn:M³ Acti- Rapid mole mole vation Polymer- M³ ratio, ratio, Time, ization, Designation Compound prep product min min Ex. 12 Mo (IV) 1:11.3:3.3 1:1.8:3.8 30-40 140-160 oxide Ex. 13 Co (II, III) 1:11.3:1.1 1:0.7:1.0 −30 100-110 oxide Ex. 14 W(VI) 1:11.3:3.3 1:2.0:3.2   33 90 oxide Comp. C* None 1:2:0   55 180-190 *Not an example of this invention.

All of Examples 12-14 demonstrate faster activation and earlier onset of rapid polymerization than does Comp. Sample C.

EXAMPLES 15-21 AND COMPARATIVE SAMPLES D-H

Preparation of zinc hexacyanocobaltate catalyst complex. A mixture of zinc chloride (48.00 grams, 352.1 mmol), tert-butyl alcohol (60 mL), and deionized water (60 mL) are heated to 40° C. in a round-bottomed flask. Aqueous HCl (144 μL, 0.001 M) is added to the flask and the mixture is stirred for 10 minutes are ambient conditions. Next, a solution of potassium hexacyanocobaltate (10.37 grams, 31.2 mmol) premixed with water (80 mL) is added dropwise over a period of 2.5 hours. The mixture is then heated under reflux until a white gel forms (approximately after a period of 20 hours). The resultant gel is dispersed in water (180 mL) and tert-butyl alcohol (180 mL) and then centrifuged (5000 rpm) for 15 minutes. The solvent is decanted and the resultant material is again dispersed in a mixture of water (180 mL) and tert-butyl alcohol (180 mL). The resultant dispersion is heated to 55° C. for 35 minutes and then centrifuged (5000 rpm) for a period of 15 minutes. The resultant material is then washed four times with a 50/50 by volume mixture of distilled water and tert-butyl alcohol and then washed once more with tert-butyl alcohol (180 mL). The washed material is dried under vacuum at 60° C. overnight to a constant pressure (<10 mbar). The resultant dried solid is milled, forming a DMC catalyst sample in the form of a finely divided powder. This is designated Comparative Sample D

To make Examples 15-21 and Comparative Samples E-H, a one-gram portion of the Comparative Sample D is slurried in a mixture of t-butanol and an M³ metal compound as indicated in Table 5. The amount of Comparative Sample D is enough to provide approximately 0.2 grams, or about 3.39 millimoles, of cobalt. The resulting slurry is again centrifuged, dried as before and milled. The result in each case is a physical mixture of particles of a zinc hexacyanocobaltate complex and particles of the M³ metal compound. Some agglomeration of the two particle types may be present.

Examples 15-21 and Comparative Samples D-H are evaluated for activation time and time to onset of rapid polymerization, using the polymerization method described with regard to Examples 1-4. Results are as indicated in Table 5.

TABLE 5 Onset of Co:M³ Acti- Rapid Millimoles metal vation Polymer- M³ M³ mole ratio Time, ization, Designation Compound compound (estimated) min min Ex. 15 Mo(VI) 1:1.9:1.9 30-40 95 oxide Ex. 16 Fe(III) 2.24 1:1   20-25 120 oxide Ex. 17 V(V) oxide 4.49 1:1.5 40 130-135 Ex. 18 MgO 4.49 1:3.9 30 125 Ex. 19 Sn(IV) 4.49 1:1.7 50 180-190 oxide Ex. 20 ZnO 4.49 1:1.8 30 180-190 Ex. 21 NiO 2.24 1:2.1 40 130 Comp. D* None 0 1:0   55 180-190 Comp. E* Sb(III) 4.49 1:1.2 40-50 250-300 oxide Comp. F* CaO 4.49  1:1.36 Catalyst Does Not Activate Comp. G* BaO 4.49 1:1   Catalyst Does Not Activate Comp. H* CuO 4.49 1:2.3 >300 >1000

Examples 15-21 exhibit shorter activation and/or onset to rapid polymerization times than does Comparative Sample D. Catalyst mixtures containing the antimony, calcium, copper and barium compounds perform even more poorly than the control.

EXAMPLE 22 AND COMPARATIVE SAMPLE I

Comparative Sample I: A 260 molecular weight glycerin propoxylate, (115.6 g) is propoxylated with 84.4 grams of propylene oxide using the general polymerization conditions described in Examples 12-14. The catalyst is 0.3 g of a commercially available zinc hexacyanocobaltate catalyst complex (enough to provide 150 parts per million based on the expected mass of the product). The catalyst does not activate even after 275 minutes.

Example 22 is made performed in the same manner, except that 0.168 g of aluminum oxide having a surface area of about 155 m²/gram is added to the mixture of dipropylene oxide and zinc hexacyancobaltate. The catalyst activates after about 35 minutes, and the onset of rapid polymerization occurs occur even after about 110 minutes. A polyether triol having a molecular weight of about 425 is obtained.

The conditions of Example 22 are even more severe than those of the previous examples because of the use of the trifunctional starter and low equivalent weight (about 140) of the product. The hydroxyl concentration even at the end of the polymerization process is 12%. 

The invention claimed is:
 1. A method for producing a polyether, the method forming a reaction mixture comprising a hydroxyl-containing starter, at least one alkylene oxide and a catalyst complex, and polymerizing the alkylene oxide onto the hydroxyl-containing starter to produce the polyether in the presence of no more than 0.01 moles of a carbonate precursor per mole of alkylene oxide, wherein the catalyst complex is a mixture of a zinc hexacyanocobaltate catalyst and a particulate M³ metal or semi-metal oxide wherein the M³ metal or semi-metal is one or more of aluminum, iron, hafnium, gallium and indium and the M³ metal or semi-metal oxide is present in an amount sufficient to provide 0.002 to 10 moles of M³ metal or semi-metal per mole of cobalt provided by the zinc hexacyanocobaltate catalyst, and further wherein the hydroxyl concentration during at least a portion of the polymerization is in the range of 4.25 to 20% by weight of the reaction mixture.
 2. The method of claim 1 which is semi-batch process in which the catalyst complex and hydroxyl-containing starter are charged to a reaction vessel, the catalyst complex is activated and at least a portion of the alkylene oxide is thereafter added to the reaction vessel containing the activated catalyst complex and hydroxyl-containing starter under polymerization conditions without removal of product until all of the alkylene oxide has been added.
 3. The method of claim 1 which is continuous process in which the catalyst complex, hydroxyl-containing starter and alkylene oxide are fed continuous to a reaction vessel under polymerization conditions and product is continuously removed from the reaction vessel.
 4. The method of claim 1 wherein the hydroxyl-containing starter has a hydroxyl equivalent weight of 30 to
 200. 